I imagine ambulances save more lives than automobiles take.
Ambulances would need to save their passengers' lives <1% of the time for them to "break even" so to speak.
[0] https://en.wikipedia.org/wiki/List_of_motor_vehicle_deaths_i...
Even the emergency trips, it's difficult to say whether the person would have died if they didn't have an ambulance.
Overall this would be pretty hard to quantify.