The researchers supposed that this planet might have iron and titanium in the atmosphere, they have an image of the star with a slight dimming from the passing of the planet across it, and they find the spectral signature of iron and titanium.
The percentage of the light collected that was emitted by iron and titanium, if it existed in the atmosphere, would be so mind-boggling minuscule compared to the light of the star itself, I would think that the iron and titanium signatures would come from elements trapped in or around the star.
I think if they looked hard enough they could find whatever elements they want.