Because Requests makes HTTP much easier to work with, which has dramatically expanded the pool of developers who are comfortable doing that kind of work.
When we've had to add some level of concurrency to an HTTP tool, we have serious discussions over whether to swap out Requests, or to just run multiple instances of the tool, especially if it's a tool that only requires concurrency sometimes.
This is nothing against aiohttp or others, but Requests is de facto standard library.