Most pollution comes from the energy used by motors to move people from one place to another, which is obviously more in a suburb environment rather than an walking environment.
https://www.epa.gov/ghgemissions/global-greenhouse-gas-emiss...
Largest sector globally is industry and heat, followed closely by agriculture.
Big cities may be superior in some respects, but they are also the symptom of a larger problem - it’s a lot more of us on this planet than were pre-industrial.
Ultimately, poking people in the eye about their consumption habits is counter-productive. Cities are efficient, but not efficient enough to prevent global warming. This problem is only going to be solved through technical innovation and government regulation.