I thought part of their managed service was that they optimized / tuned your postgres db based on how you were using it. If that is true, then moving off of the managed service means you are tuning postgres yourself now.
Also want to throw in there that it is important to not only compare specs, but to also compare hardware. If DO has newer chips and faster RAM, then you will take a performance hit moving to the new provider even if the machine is beefier.