Oh, I think I wasn't careful enough with my language.
I meant that the common ordering on tuples is reasonably natural. Not that it is necessarily the One True Natural Ordering.
About lattices and partial orders: if there's a choice about what to pick as the default ordering for some built-in datatypes for your language and there are multiple reasonable choices, going with the total order seems like a good idea.
To give a counterexample: functions from natural numbers to an orderable set have a well defined, reasonably natural order, just compare them like as if they were a list of elements of the orderable set. But that would be a bad idea in a programming language, and it is indeed better to just treat functions as incomparable by default.