The CAs are hard embedded in the core snap. They're pulled from some specific package when built, but snaps themselves are immutable. We attempted to overwrite it in several different ways, but the OS is just simply mounting these folders from the core snap (which is immutable), and then marking those mounted paths them as immutable.
That being said, there are a list of paths you can write to, and they're listed here (for core18): https://github.com/snapcore/core18/blob/master/static/etc/sy...