TechZing Live straddles the border of software engineering and startup discussions depending on the topic:
https://www.dropbox.com/sh/frnqzndys9j3vc1/P7jHgH0BQK
It's the full TechZing catalog.
From episode 1 to 300+ TechZing is a 10 year journey of friendship, tension, hacker talk and bootstrapping.
Of note, we were first to interview at least two founders who went on to build unicorns (Patrick Collison, Travis Kalanick) and many more who are now household names in the startup scene.