This withdrawal fee they have is a confounding variable to interpreting the prices of the options on Predictit.
I've seen many slam dunk contracts trading at $0.96 or $0.97 a share. At first I thought it would be a good idea to buy as many as the platform would allow me, and get the guaranteed 4ish% percent return. But then I remembered the withdrawal fee and realized I'd still lose. And then realized that any other potential buyer would do the same.
I suppose if you already have money deposited there, and don't know where else to park it, then buying these contracts would be the in-universe equivalent of "parking it in treasuries." But I'd expect the pricing to become more accurate if that 5% transaction cost was eliminated.