Without the user's consent (and their share of the royalties)? Regardless of their TOS, how would that stand in a court of law?
It's still shady that they can resell your work in commercial channels other than the TwitPic service itself, but it's not like they obtain total control and ownership of your pictures.
IANAL, this whole post may be and probably is wrong. Please correct me.
None of this is legal advice, just broad overview for the purposes of a purely academic discussion. There are a lot of details that are omitted, so do not rely on anything said here but consult your own attorney instead.
If it's not, I guess you can go after the app developer's for damages.
Example: The purpose of the app is different now than it was when they signed up