As it produces 100W of electricity, the RTG also produces way more energy as heat. According to Wikipedia, the efficiency of an RTG is usually around 3% to 7%, so you get kilowatts of heat.
https://en.m.wikipedia.org/wiki/Radioisotope_thermoelectric_...
So, it's same order of magnitude to my electric space-heater, if it was stuck to "on". I trust Andy Weir's calculations on whether it is about right to keep a botanist warm on Mars.