The company that was pitching my employer retina scanners on data center doors 20 years ago had an idea like this. Left eye gets you in, right eye gets you in and alerts security.
Heck. You could set it up so that it scans both eyes and then does a second scan where you choose what your ok signal is (both eyes, right only, left only, no eyes).
It’s been done before: https://m.youtube.com/watch?v=rufnWLVQcKg
A PIN disarms the alarms system, the same PIN + 1 disarms the alarm system and notifies security.
Edit: made it make sense