These supposedly worked on the principal that peoples voices would create vibrations on window glass and that by shining a laser beam on said window, it was possible to demodulate the observed laser changes back into sound.
I heard rumors that certain 3 letter agencies used more powerful particle beams to penetrate heavy curtains and other sound dampening measures employed in embassies as counter surveillance. As I heard it, the curtains needed to be changed on a regular basis due to them becoming radioactive.
If these devices actually existed and miraculously worked I would be very impressed with the operators that managed to calibrate them, given all the unknown variables presented in the field.