If deuterons could fuse with other deuterons in a metal lattice, this would have been seen ages ago, just by accelerating deuterons into a deuterium-loaded material. This is how neutron generator tubes work, and they've been used for longer than you've probably been alive.
What happens in these tubes is the vast majority of deuterons lose energy by ionization and don't undergo nuclear reactions. There is no radical increase in fusion from electron shielding.