Could we use it as a diet food if it’s indigestible?
As others have commented, no. 2 yellow field corn can be ground into cornmeal, and even without nixtamalization, it is certainly digestible by humans, it's just that nixtamalization makes important nutrients like niacin available.
I agree with you in that fat, by itself, does not promote weight gain. It's the combination that does.
[0] https://smile.amazon.com/Why-We-Get-Fat-About-ebook/dp/B003W...