Have they released any images of the galactic center yet?
So roughly speaking, since you cannot really compare the two, since they observe on quite different wavelengths, EHT has ~4000 times better resolution than Webb. Note that we don't speak about sensitivity here. ALMA array of radio telescopes has a collecting area of 7000 m2, while it is just one of many "nodes" of the EHT. Webb total collecting area is about 25 m2.
1. https://www.jwst.nasa.gov/content/about/faqs/faq.html#sharp