If an attacker were to obtain the PSK and use a quantum computer to break the Diffie-Hellman key exchange, they would be able to decrypt the VPN traffic.
This is currently the thought-process and main reason behind why PQWG (Post Quantum Wireguard) are actively being researched [1].
Not sure what you're trying to say here. If you share the PSK out-of-band, securely, then wireguard is quantum resistant (I wouldn't say quantum-safe, because I'm not that optimistic).
> If an attacker were to obtain the PSK
Indeed if the attacker obtains the PSK then obviously the PSK isn't going to help you.
I believe it is traditional, in most threat models, to assume that the attacker doesn't have your private keys.
We are :) Rosenpass is a fancy way of generating a PSK for WireGuard.
Because key exchange and key rotation is a huge problem.