PRQL has a data model very similar to the relational one. The only big difference is that relations are ordered - they are defined as arrays of tuples. So let's hope that PRQL gets to be known as "the relational language Mk II"
Ordered tuples like you say, but also duplicate tuples. And null values.
There's also a DBeaver plugin [3] which we still need to document better and simplify the usage of but you could potentially also use that to query Postgres with PRQL.
Finally there is pyprql [4] with which you could query Postgres from a Jupyter notebook.
[1]: https://github.com/ywelsch/duckdb-prql
[2]: https://duckdb.org/docs/extensions/postgres_scanner.html
[3]: https://github.com/PRQL/prql/issues/1643
[4]: https://github.com/PRQL/pyprql
(Disclaimer: I'm a PRQL contributor.)