It is not. That is pin D71, SCL1 (emphasis on the 1) - the Due has two indepdendent i2c busses. It makes a similar error regarding pin D70, just below it.
It also fails to note that D10 = D77 and D4 = D87, and that both of those pins (in addition to D2, D3, D4, D5, D11, D12) support PWM. Frankly the listing of the PWM column is confusing, in general, for the Due, with what is labelled and what isn't.
Contrast: https://forum.arduino.cc/t/due-pinout-diagram/129258
Admittedly, these are carrying forward errors in the official documentation, but these errors have been known for a very long time (they were updated in the unofficial pinout I link in 2013).
Unfortunately, offering only a monochrome (yet unprintable) view, leaving pins (connectors in the center of the board) unlabeled, and carrying errors forward means I don't see a particular use for this document.