Calling bullshit. Semiconductors cannot be "improvised". PN junctions aren't found anywhere accidentally.
https://en.wikipedia.org/wiki/Foxhole_radio One common type was made from an oxidized razor blade (rusty or flamed) with a pencil lead pressed against the blade with a safety pin. The oxide layer on the blade and the point contact of the pencil lead form a semiconductor Schottky diode and only allow current to pass in one direction.