My understanding is also that MPTCP will send data over the backup link, which can incur data charges. Those charges shouldn't be very big, but I've seen carriers who round data up to the next megabyte, and a single background handshake at night can eat through your data cap surprisingly fast.
I would hope whatever data savings systems are built into mobile operating systems take care of this automatically, but I can see why one could want to disable this by default on mobile operating systems.