This is why:
http://www.google.com/search?q=php+mysql
Searching for PHP and MySQL yields tons of tutorials, code examples, and documentation related to the now-deprecated mysql interface. When I wrote my first comprehensive PHP application last year I spent half a day trying to determine best practices before finally settling on PDO. Newbies won't go through that effort, and will naively land on mysql rather than PDO or mysqli as likely as not.