As humanity becomes more numerous and richer, the fraction of humanity you need that have such strange ideas and desire keeps shrinking.
(Btw, I share your intuition that the number of people willing to sign up for a one-way trip to the stars, or even just Mars, is fairly low. However, if you already look at people who are dedicated enough to become astronauts, I suspect the additional filter of asking for one-way-trip volunteers for a mission to the stars isn't all that severe. My purely speculative guess is that at least 10-20% of current astronauts would be willing to sign up.)