As I understand, the serving temperature of coffee does have an effect on perceived acidity (which is NOT the same as pH), though I don't understand the science behind it. Here is one paper that claims it is due to release of volatiles at higher temperatures: https://www.sciencedirect.com/science/article/abs/pii/S03088...
If that's correct, then warming the coffee again to that temperature would again speed up the release of volatile compounds, though what effect that might have on flavor is anyone's guess.