No, only on Intel.
From the "Requirements for certifying Windows 8 systems" PDF available at http://msdn.microsoft.com/library/windows/hardware/hh748188 :
MANDATORY. On non-ARM systems, the platform MUST implement the ability for a physically present user to select between two Secure Boot modes in firmware setup: "Custom" and "Standard". Custom Mode allows for more flexibility as specified [...]
On an ARM system, it is forbidden to enable Custom Mode. Only Standard Mode may be enabled.