Correlation/Causation: lots of things in graphics rendering work because of observed phenomena. A “good graphics engine” is only as good as the eyes that implemented it. Todays engines still fall short of what is in front of us, and not because of a technical limitation.
> Pretty sure I saw scenes where shadows were purple despite a green sky.
If it’s a stylistic effect then it’s a stylistic effect. But otherwise, purple shadows are literally everywhere. Shadows can have an immense amount of chroma and vibrancy to them, or they can be incredibly cool and muted. It all depends on the context.