In general, my UI gripes:
* Bookmarks dialog from the 90s, various usability issues
* History dialog, same
* Lack of Tab Groups, still, and no plugin has given me the experience as Safari
* Profile switcher UI is also terrible
* Still no vertical tabs
* Still nothing like Safari "tab overview"
* Miscellaneous UX fails like not being able to hover over a Tab preview and close it without switching to it (like the 'x' on List All Tabs) or close a tab by hovering over a persistent x without switching to it
* Create bookmark dialog is limited so a small size and can't fit more than a few location folder entries
* macOS : after all these years, still can't full-screen like a normal macOS app (all app bar toolbars / chrome shift when mouse)
I can't remember an interesting UI feature in at least several years.