The account number is the unique identifier assigned by the bank. Your card is the physical "key" (password) to said account, and the PIN is your self chosen identifier (username).
Think of it this way: I can tell you my pin number and my bank account number all day long, it doesn't matter if you don't have my card. But if you had my card, you'd have a reasonable shot at guessing the PIN and gaining access. The card is the password.