I, for example, still find it very difficult and unnatural to smile for photographs unless I am already smiling about something else and the picture is just a candid moment caught at that time.
I would imagine that this old picture taking process (3 separate pictures with different filters each time) took quite a bit of time and subjects had to be posed for a a longer period of time. It would be very difficult to hold a smile for that long, and especially in those early photography days when the smiling-for-pictures convention still hasn't been established.