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Quite some time ago I implemented NFS for a small HPC-cluster on a 40GBe network. A colleague set up RDMA later, since at start it didn't work with the Ubuntu kernel available. Full nVME on the file server too. While the raw performance using ZFS was kind of underwhelming (mdadm+XFS about 2x faster), network performance was fine I'd argue: serial transfers easily hit ~4GB/s on a single node and 4K-benchmarking with fio was comparable to a good SATA-SSD (IOPS + throughput) on multiple clients in parallel!

Yes, you might want to tune your NFS parameters, stick to NFSv4.2, consider if caching is appropriate for your workloads and at what level, and how much of your NFS + networking you can keep in kernel space if you decide to further upgrade your network's throughput or really expand it.

Also consider what your server and client machines will be running, some NFS clients suck. Linux on both ends works really well.

The last time that I looked, OpenBSD does not support NFSv4 at all.

Consider BeeGFS. Had good results with it using infiniband.