Actually there is, given that the reference compiler depends on C++.
Just look at how long it took LLVM to catch up to GCC. Writing a competitive optimizer pipeline is hard work.
"No room for a language above assembly and below Rust" is a design goal for what it's reasonable to build with it.
If anything, using LLVM for the default backend is completely on-brand with how much priority Rust puts on being suitable for partially or incrementally rewriting C codebases.
(Sorry for the slow reply. The tab got buried.)