I use Google Apps (possibly not a good idea but soo convenient :/) with a catchall. I didn't catch any offender so far...
However (off topic), spammers are spoofing addresses as if they were coming from my domain. I receive two to three dozens automatic replies from mail servers (this address does not exist...).
I've properly set up DKIM and SPF records, making it obvious that these mails are spoofed, but I'm afraid my domain will end up on grey/black lists... Anyone out here familiar with this kind of issue?