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One thing the EU has not done is threaten to use economic coercion to force annexation, as the U.S. has done repeatedly. If becoming an associate member of the EU involves some loss of sovereignty, it will probably be less than we'd surrender by choosing not to diversify our trade away from the U.S..
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[1]https://www.reuters.com/world/americas/carney-pushes-idea-ma...
No-one’s talking about Canada joining the EU. And ah, leaving the EU is fairly obviously possible; see the UK.