Also, as you can see from the Russian billionaires on the list, many influential people have made vast fortunes when state-owned monopolies were "privatized" and became privately-owned monopolies.
I think Mexico can be more easily grouped with the BRIC countries, rather than, say, Kenya and Cambodia.
I guess the only point I really want to make is that naming and labeling is a difficult problem, even outside of computer science.
http://business.blogs.cnn.com/2012/01/12/worlds-top-economie...
Point is: if you redirect money from where it was intended to be, you can make a lot of money. Especially in 3rd world countries where systems to keep this behavior in check are too weak or non-existent.
(I don't know how Mr.Slim made his money though; I'm commenting more on the surprise for billionaire's from 3rd world countries)