Will browsers immediately fail the connection, or will it try to make the connection and wait for a timeout? I generally use 0.42.42.42 because Class-A addresses can't start with 0, so they fail immediately.
$ curl --connect-timeout 5 -v 192.0.2.1
* About to connect() to 192.0.2.1 port 80 (#0)
* Trying 192.0.2.1...
* Connection timed out after 5011 milliseconds
* Closing connection 0
curl: (28) Connection timed out after 5011 milliseconds
So your browser will likely end up trying the connection and timing out after a while.