The words are separated (and I guess terminated) by a random symbol (of which there are apparently 32 possibilities) or (randomly) a random two-digit number. log(50000^4*(100+32)^4)/log(2) = 90.6
Doesn't that defeat the "Trivial to remember" part of the xkcd concept of "Trivial to remember, hard to guess?"
That means you only have 7 entities to remember, which is supposed to be what humans can handle easily. (Though I understand now that this is stale knowledge.)
The number refers to the capacity of working memory and has indeed been revised over time. It's a complicated issue, but 4 units of information is now considered a more accurate approximation. But if you're remembering a password, you're dealing with long-term memory, which doesn't have this limitation.
Long-term memory usually accepts most information from short-term memory not direct sensory input, so it is easier to memorize when you break down things in chunks first.