An organic fungicide: copper sulfate pentahydrate (aka CuSO4)
A non-organic fungicide: iprodione (aka Rovral)
LD50 of CuSO4: 472 mg/kg (rat) [1]
LD50 of Rovral: 2g/kg (rat) [2]
So straight up, the organic is four times more lethal to mammals. But that is just the beginning, because you have to use a lot more of the organics! How much would Farmer Joe have to use on his small, 10 acre plot? Assuming the worst, lets look at the maximum seasonal application.
rate of CuSO4: 16 pounds/acre per season [3]
rate of Rovral: 12 pints/acre per season [4]
Skipping the basic algebra, in one year Joe could apply enough organic fungicide (72.5kg) to kill 1700 people. One year of non-organic (1.3kg) would be enough to kill 7 people. (Assuming a spherical man of 90 kg.)
[1] http://extoxnet.orst.edu/pips/coppersu.htm
[2] http://www.cdms.net/ldat/mpAKR005.pdf
[3] http://growabundant.com/copper/
[4] http://www.cdms.net/ldat/ldAKR006.pdf
edit: ambago, you are full of bunk. The USDA has very strict guidelines for labeling. See http://en.wikipedia.org/wiki/Organic_certification