I personally prefer RAII to finally for object-related cleanup because finally is fallible. If you have a File object instance whose destructor calls fclose() automatically then I don't have to remember to call a Close() method inside a finally block. It happens automatically. But if you don't have RAII then you must remember to put in try blocks and finally clauses everywhere you create an instance. Multiply that by every database connection, network connection, and file and that is a lot of work and potential to miss something. And finally doesn't work at all if your object lifetimes aren't tied to scope.
Finally is inferior to RAII in almost all cases except where you aren't using nicely defined objects. If you use an fopen() call directly, finally is your only recourse to fclose() it properly. The only criticism of RAII is that does limit concurrency and garbage collection options.