I've tried to get people on here interested in the show before:
http://news.ycombinator.com/item?id=761443
I think it's a great show and I really like seeing all the different business ideas. Most of the founders seem to make mistakes in the negotiations but I think there have been some pretty good deals on the show so far.
I definitely recommend watching it, either live or on Hulu, it's one of the best shows on TV and definitely one of the best reality shows, other than The Colony.