Make it
look like a prototype? I've taken to plastering big warning on non-production systems. Otherwise someone looks at a fragile dev environment, doesn't see it breaking outright, then goes and sells live customers into it and uses the prototype/demo system to setup real accounts. No amount of verbal or email warnings will change this. Hurray, now the one-off demo system is a production environment! As a bonus, you get to write data migration programs to move these customers to the entirely-unrelated final product!
But instead, if there are big red Xs and so on in the UI, then it becomes clear "oh this is a prototype/demo/".