These things aren't impossible, but it's such an uphill battle that I wouldn't hold my breath. (http://jalopnik.com/why-the-solar-roadway-is-a-terrible-idea...)
From a material perspective glass is much closer to concrete than asphalt. Ex: http://en.m.wikipedia.org/wiki/Glass_brick the point being glass withstands sunlight and the elements without issue, it's being driven on that's going to be an issue. And luckily that kind of stress is much easer to simulate in a lab vs weathering.
PS: That or ice which can handle heavy loads with little issue.
For this to work you have to do several things to the glass at the same time, none of which come easy: make it strong, make it hard (probably need to get to 8 or 9 on Moh's hardness scale), make it tough, and have it grip rubber as well as asphalt does even when it's wet. Considering scratch resistant and grippy compete with eachother this is not looking hopeful.
The advantage being rail lines need to trainsport electricity for electric trains, so you get dual use from those power lines.
PS: Bullet resistant glass is surprisingly clear dispite how thick it is.
Personally I think Elon Musk's solutions for this problem (decentralized clean power generation) are a bit more compelling, especially the part about putting solar panels on our rooftops instead of in our roads.
http://fusion.net/story/129075/elon-musk-reminded-everyone-l...
This fixation on "we're already using land area for roads; solar panels need land area; lets combine them!" is not an engineering decision - its politics and public relations.
Here's an excellent engineering analysis of this exact project: https://www.youtube.com/watch?v=HOZBrHqTJk4
Local council governments may have access to its road real estate, but have no legal right to install panels on roofs. Netherland land value, per square meter, is €4,907. There is a local property tax is 0.05% - 0.3%. (http://www.shelteroffshore.com/index.php/property/more/prope...), and a wealth tax of 1.3% per year. Assuming 1.4% total taxes per square meter, the revenue received by the government is €68 per square meter. Since building the solar panel on the road means they don't have to build solar panels on real estate that can generate tax revenue, the benefit is €10 of generated electricity, plus the €68 of tax revenue that is preserved (assuming all municipal building rooftops are exhausted, already). That makes a payback of €78 per year. In 15 years, this would equate to €1170, compared to building a solar array on free land. The savings would be even greater compared to the local government renting rooftops to place solar panels.