There is also a section in the readme explaining the differences with the most used libraries: https://github.com/FullHuman/purgecss#differences-with
4 karma · joined July 14, 2017
Purgecss will not emulate the dom and execute javascript. Instead, it will read your files, determined the selectors in it and then remove the ones that are not used. A much simpler process that will translate in better performance.