Awesome project!
If you support mic input, you can allow the user to select a device as the "nexus" with mic recording on. Then you tell each device in your setup to "chirp" at the same exact time, but at different frequencies. Then you can derive the individual device's "local delay" and compensate.
This allows you to tune the surround setup to full accuracy for a given point in space, and it will take care of ring buffer differences, wireless transfers of non-teathered speakers, etc.