Though that will result in a lot more calls to Count(). A let would fix that.
from word in text.Split(' ')
group word by word into g
let count = g.Count()
orderby count descending
select g.Key
Under the covers when it is compiled it's turned into a select. That way it it only does N counts, not potentially N log N (for each comparison in the orderby), where N is the number of items you enumerate (so if you .Take() just 10 it doesn't really matter).